Updated: Dec 21, 2019
Emergency Planetary Technician and Climate Science Wonk — using naturopathic remedies to recover the Holocene without geoengineering or ponzinomics.
Jun 25 (This essay is part of a forthcoming book, Carbon Cascades from Chelsea Green, due Summer 2018.
Pantheon, Rome. Panorama by Einblick
We want to take the atmosphere back to its pre-industrial state as quickly as possible. For that, we have biocomposites.
Webscreen-grabbed the above images off earth.nullschool.net when we were looking at Tropical Storm Cindy on June 19. The top image shows Earth’s oceans. Red is hotter than normal. Blue is colder than normal. The Polar seas are colder than usual because of all the fresh ice water from melting glaciers and ice shelves.
The lower image is the same moment, looking at the land masses too. There are simultaneous heat waves in North America, S. Europe, Africa, the Middle East, India and parts of China, setting temperature records for the date, all the way around.
Kathleen Draper is US Director at Ithaka Institute for Carbon Intelligence. In addition to editing The Biochar Journal, the leading on-line biochar magazine, Draper researches carbon intelligent cities; climate farming: nutrient recycling and GHG reduction in livestock farming; biochar characterization and optimal usage recommendations; closed loop biochar production and use modeling; ecosystem remediation; land management and landscape design. She has worked with Cornell University to model the Triple Bottom Line impact of Combined Heat & Biochar unit at the urban aquaponics greenhouse in Central New York.
Working with the Rochester Institute of Technology, she developed the Filtration to Fertilizer strategy using biochar first to harvest nutrients in effluents from food & beverage industries — including rentals to tofu shops — and then sales of nutrient-saturated char as a soil amendment/fertilizer for greenhouse crops. She is also working with RIT on the use of biochar in sustainable building materials, packaging materials, filtration media for the food industry and heat recovery options for the Kon-Tiki kiln technology.
A few days ago Kathleen Draper penned to her blog:
Last week I visited a small slice of heaven; The Farm in Summertown, TN. The Farm is [one of] the oldest intentional communit[ies] in the country and has been home to Albert Bates, author of The Biochar Solution amongst other books, for decades.
Biochar experimentation at The Farm spans the gamut from soil amendment to building material to humanure additive which then moves over to worm bins for some final processing. Just walking around the various natural buildings and permaculture filled ambiance was enough to inspire, but actually getting my hands dirty making biochar plasters, cement mixes, bricks, filtration devices with other like-minded folks was soul boosting.
We visited a nearby farmer that feeds his livestock (pigs, goats, poultry) an earthy blend of biochar mixed with lightly fermented whey and grains which they gobbled up greedily. We used rather grand outhouses that mitigated odors and reduced nutrient leaching with a blend of biochar and sawdust. And we shared stories of our mutual journeys, lessons learned and best practices along the biochar continuum.
What I really enjoyed about this experience, especially compared to attending biochar and other related conferences which tend to pack an enormous amount of information into back-to-back 15–20 minute sessions all day long for 3 days, was the more relaxed pace, the ability to get to know everyone there and hear about their own particular biochar experiences. The other fun part was leveraging everyone’s tools and backgrounds to take certain ideas further — such as the chardboard paper which I wrote about nearly 3 years ago. Albert had a contraption that was able to measure the electromagnetic shielding of the chardboard which was pretty substantial,
roughly 90% reduction! (click the link to see the short video on Instagram)
For those of you that have the time and desire to experience truly sustainable living, I highly recommend a visit to The Farm. Staying in the Fairy House, a cozy earthbag building with a living roof provides the quietest sleep you could ever dream of….
We liked having Draper here for the workshop but can’t let her escape with just this short report to the public domain. She and Dr. Hans-Peter Schmidt at the Ithaka Institute in Switzerland brought to our course a wealth of information on the practical applications for biochar when removed from the agricultural sphere. They are co-authors, with Ute Scheub and Hailko Pieplow, of Terra Preta: How the World’s Most Fertile Soil Can Help Reverse Climate Change and Reduce World Hunger.
Hans-Peter beamed into the workshop via Skype and together with Kathleen provided a picture of a new realm of biochar that we had been nearly unaware of — as biochar concrete, or “char-crete”
Firstly, there is a global problem with concrete and it is getting bigger. The most important part of concrete is Portland cement, the binding agent made from pulverized limestone (calcium oxide) and clay (silicon oxide), heated together at high temperature (2700F).
Pantheon Oculus, 126 CE
The discovery and refinement of Portland is a cautionary modern tale of the intersection of materials and manufacturing at the dawn of the fossil fuel era. The Romans and Chinese had millennia ago discovered that gypsum and lime could be mixed with pieces of rock, sand, ceramics or rubble to form a hard material that would hold up to weather, or even set up underwater for dams and bridgework. Roman concrete, developed from 150 BCE, is durable due to its incorporation of volcanic ash and cinders (pozzolana), which prevents cracks from spreading. After the famous fire of 64AD, Nero rebuilt much of Rome with brick-faced concrete. The Pantheon in Rome, with its 142-foot coffered dome and oculus, is an example of Roman concrete construction still standing after 2000 years.
Lime is a powder that wants to be a rock. It has a million-year memory. Formed as the aggregated dust of seashells on an ancient sea-bed, limestone (CaCO3) gets unpacked from its bed in some quarry, hauled by truck to a kiln, and baked at >1500°F. The burn drives off CO2 and leaves behind a powder (CaO), called burnt lime or quicklime.
Quicklime (calcium oxide) is a white, caustic, alkaline, crystalline solid at room temperature, but feeling an urge to go back to rock, it will draw CO2 from the air unless slaked with water. Slaked lime is what the Romans and Chinese used for mortars and plasters. It is what Michelangelo in 1511 spread across the ceiling of the Sistine Chapel and painted the image of God into. In the 1820s scientists learned that when heated to >4,000°F (2,200°C) it emits an intense glow. That feature was used broadly in theater productions before electric lighting — limelight.
As it slakes, quicklime releases heat by the following equation:
CaO (s) + H2O (l) ⇌ Ca(OH)2 (aq) (ΔHr = −63.7 kJ/mol of CaO)
When limestone is kilned to make lime for mortar or cement 1.8 tons produces 1 ton of CaO. The missing 0.8 goes to the atmosphere as CO2 and a few trace impurities. China is by far the world’s largest producer, burning enough rock to produce around 170 million tons per year. The United States is the next largest, with around 20 million. Worldwide, lime kilns send about 225 million ton of CO2 to the atmosphere. File that number away for a moment.
If you add an atom of carbon to quicklime in the presence of oxygen, you get limestone and water.
Ca(OH)2 + C + O2 = CaCO3 + H2O
That limestone molecule can take a much-deserved rest. It has now completed a full revolution on the wheel of life and rebirth.
Suppose that, instead of leaving it to chance, we supply lime with carbon? One easy way to do that would be to mix biochar with cement and let it harden in the open air. You could replace sand in concrete or mortar. This is convenient because construction-grade sand is getting harder to come by and is experiencing rising demand (and price).
But here is the kicker. The resulting concretes or mortars have improved:
• Weight (biochar is significantly lighter than sand)
• Compression strength
• Flexural strength (MOR)
• Curing (soaking the carbon into the lime)
• Capacity to absorb CO2/NOX
• Electromagnetic shielding
• Fire resistance
• Humidity control
• Indoor pollutant control (dust, pollen, chemicals).
Run the Research
What does the research say? Choi et al (Mechanical Properties of Mortar Containing Bio-Char From Pyrolysis, 2012) tested char-cretes at 5%, 10%, 15%, 20% biochar and found:
• All biochar admixtures had less weight loss due to moisture evaporation. Mortar mixes with char have better water retention. This may lead to improved strength. “In this way, biochar seems to play a role as a self-curing agent.”
• The workability of mortar decreases as the percentage of biochar increases.
• 5–10% biochar replacement is similar to 20% replacement with fly ash (the toxic residue of cement making and other industries).
• Up to 5% biochar shows an increase in compression strength.
A study by Restuccia et al, Promising low cost carbon based materials to improve strength & toughness in cement composites (2016) tested the mechanical properties of cement using biochar made from coffee powder (unroasted discards) and hazelnut shells.
• All char additives outperformed control bending strength, compression & fracture energy.
• Coffee powder did better on compression tests.
• Hazelnut shells did better on flexural (MOR) and fracture energy tests.
• Hazelnut shells’ irregular morphology creates “perfect bond with surrounding matrix.”
• Coffee powder has higher silicates which could work as an accelerator helping to speed up the hydration process. It stabilized at 7 days.
A study by Khushnood et al, Carbonized nano/microparticles for enhanced mechanical properties & electromagnetic interference shielding of cementitious materials (2016) tested mechanical & shielding properties of cement using peanut shells and hazelnut shells at 6 different concentrations.
• All cha